Washing Step
Hot wet-processing cycles for printed and dyed cellulose fabrics remove unreacted dyestuff and auxiliary chemicals from the yarn surfaces. The soaping off stage is the final step in reactive dyeing, where the fabric is treated with surfactants at or near the boil. This washing is necessary to prevent bleeding and to establish the final color fastness of the fabric.
Chemical Mechanism
The process uses anionic or non-ionic surfactants that disperse the hydrolyzed reactive dye that has not formed covalent bonds with the cellulose fibers. During soaping off, the washing liquor must be kept above ninety degrees Celsius to swell the fibers and release the loose pigment. This treatment holds the released dye in suspension, preventing it from redepositing on the clean portions of the fabric.
This soil-release action is followed by cold rinsing to contract the fibers.
Process Verification
Technicians evaluate the wash water and the fabric shade to ensure that the process has been completed successfully. If the soaping off is insufficient, the fabric will show poor wet-fastness and can transfer dye to other garments during household washing. Reflectance measurements of the wash bath and subsequent rubbing tests on the dry fabric confirm that all loose dye has been removed.
This testing is standard practice in commercial textile labs.
Factory Limit
This intensive washing requires large volumes of water and energy, which increases the operating cost of the dye house. Mills use counter-current washing systems to reduce water consumption.