Solubility Conversion
Chemical conversion of insoluble vat pigments into their water-soluble leuco forms enables the dye molecules to penetrate cellulose fibers. This process of vat dye reduction requires a strong reducing agent and an alkaline medium to break the internal carbonyl bonds. Once reduced, the dye exhibits a high affinity for the cotton fibers and can be absorbed easily.
This reaction is the critical pre-requisite for dyeing fabrics with high chlorine and light fastness.
Chemical Mechanism
Sodium hydrosulfite and sodium hydroxide are the primary chemicals used to execute this transformation. The hydrosulfite removes oxygen from the bath and converts the insoluble pigment into a soluble sodium salt. This change is often accompanied by a distinct color change in the liquor, indicating that the dye is ready for application.
Dyeing Practice
Immersion of the fabric occurs while the dye remains in this reduced state. After the dye has penetrated the fiber, the fabric is exposed to air or chemical oxidizers to convert the dye back to its insoluble pigment form inside the fiber structure.
Process Control
Measurement of the redox potential with an electrode system ensures that the reduction is complete and remains stable throughout the dyeing cycle.