Finish Movement
Physical phenomena describe the transfer of water-repellent chemicals from the surface of a fabric to the interior or to adjacent materials. Fluorochemical migration occurs when the fluoropolymer chains lose their orientation or move due to heat, pressure or chemical incompatibility. This movement reduces the effectiveness of the stain-resistant treatment and can lead to uneven performance across the garment.
Activation Energy
Reheating a treated fabric can sometimes reverse the effects of fluorochemical migration by pulling the molecules back to the surface. However, excessive heat during the curing process or storage in a hot warehouse can also trigger unwanted movement. When the protective layer is no longer concentrated on the outermost fibres, the fabric loses its ability to bead water.
Storage Condition
Pressure from heavy stacking in a shipping container can force the finish to migrate onto the lining of the garment or onto other pieces in the box. This transfer creates oily spots or changes the hand feel of the fabric in localized areas.
Performance Durability
Testing for this issue involves aging the fabric under specific environmental loads to ensure the finish remains stable over the intended lifespan of the product. Mills must select binders that lock the fluorochemicals in place to prevent a loss of functionality after a few washes.