Chemical Treatment
Industrial washing processes for dyed synthetic textiles use strong reducing agents in an alkaline bath to remove unfixed disperse dye from the fiber surface. The reduction clearing process is carried out on polyester after dyeing to prevent the rub-fastness of the fabric from being compromised by loose pigment. This washing step destroys the surface-bound dye without affecting the dye that has migrated inside the fiber.
Clearing Process
The bath contains sodium hydrosulfite and sodium hydroxide, which chemically break down the azo groups of the disperse dye into colorless, water-soluble compounds. This reduction clearing occurs at high temperatures, typically between seventy and eighty degrees Celsius, and is followed by thorough rinsing. This treatment is necessary because disperse dyes do not form covalent bonds with polyester, instead relying on physical dissolution within the fiber.
Any dye remaining on the fiber surface would otherwise rub off.
Quality Check
Laboratory testing of the finished fabric confirms the effectiveness of the process by measuring the wet and dry crocking resistance. If the reduction clearing has been insufficient, the fabric will transfer color to white test fabrics during rubbing tests. This check is a standard requirement for polyester sportswear and home textiles.
It ensures that the fabric complies with commercial fastness standards.
Effluent Management
The chemical waste from this process must be neutralized before discharge because the reducing agents consume oxygen in the water. Mills treat the wastewater to reduce the chemical oxygen demand.